Reactivity Documentation
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts |
| mixed with |
Metals, Elemental and Powder, Active |
Summary
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
-
May produce the following gases:
- Base Fumes
- Hydrogen
Details
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
is a reactive group.
Metals, Elemental and Powder, Active
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
mixed with
Metals, Elemental and Powder, Active
Metals, Elemental and Powder, Active
Hazard Predictions
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
Thiocarbamate esters can be reduced by alkali metals at room temperature to thiocarbamate anions or to flammable amines and corrosive thiolates and alkoxides. Reactive radical intermediates are formed (A. G. M. Barrett, P. Prokopiou, D. Barton, Chem. Comm., 1979, p. 1175; A. G. M. Barrett, P. Prokopiou, D. Barton, R. B. Boar, J. F. McGhie, Chem. Comm., 1979, p. 1173). Alkali earth metals may react in a similar way.
Thiocarbamates may release flammable H2 gas upon exposure to group II metals (Predicted, citation needed).
Potential Gas Byproducts
- Hydrogen (H2)
- Base Fumes
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