Reactivity Documentation
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts |
| mixed with |
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
-
May produce the following gases:
- Alcohols
- Aldehydes
- Hydrogen
- Ammonia
Details
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
is a reactive group.
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
mixed with
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
Thiocarbamates are related to amides and esters, classes of compounds which can both be reduced by metal hydrides and metal alkyls to form a variety of products, depending on the reducing agent used. Possible products include aldehydes, alcohols, thiols, thiocarbonyl compounds, and amines (Kammermeier, B. 2012. Reduction. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).
Potential Gas Byproducts
- Alcohols
- Aldehydes
- Hydrogen (H2)
- Ammonia (NH3)
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