Reactivity Documentation
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters |
| mixed with |
Acyl Halides, Sulfonyl Halides, and Chloroformates |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Carbon Dioxide
- Sulfur Dioxide
Details
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
is a reactive group.
Acyl Halides, Sulfonyl Halides, and Chloroformates
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
mixed with
Acyl Halides, Sulfonyl Halides, and Chloroformates
Acyl Halides, Sulfonyl Halides, and Chloroformates
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
SOCl2 reacts with esters, such as ethyl acetate, forming toxic SO2 gas and water soluble, toxic acyl chlorides, catalyzed by Fe or Zn (Spagnuolo, C.J. et al. 1992. Chemical and Engineering News 70(22):2). CO2 gas may be produced by a similar reaction of acyl halides with esters (Predicted).
Caution should be used before proceeding. Further research of comparable examples in the literature or very small scale, carefully controlled experiments may be needed to fully assess compatibility. The generation of gases may be rather slow, however confinement may lead to dangerous conditions.
Potential Gas Byproducts
- Carbon Dioxide (CO2)
- Sulfur Dioxide (SO2)
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