Reactivity Documentation
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters |
| mixed with |
Oxidizing Agents, Strong |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Carbon Dioxide
- Sulfur Dioxide
Details
Reactivity Predictions (for each pair of reactive groups)
Oxidizing Agents, Strong
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
Ethyl acetate reacts vigorously with oxidizers (Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 1570), and esters have an undefined incompatibility with nitrates (Lewis 1547).
Trimethyl phosphate may explode on contact with magnesium perchlorate (National Fire Protection Association, 1973, Publication 491M, pp. 154).
Thiophosphates may be oxidized to toxic and flammable SO2 gas by inorganic oxidizing agents (Predicted).
Esters may be oxidized to CO2 gas by strong oxidizing agents (Predicted).
Dimethyl sulfate ignites in contact with barium chlorite even at room temperature, presumably owing to formation of very unstable methyl chlorite. (Pascal, P. 1960. Nouveau Trait茅 de Chimie Min茅rale. Vol. 16.1, p. 264. Masson et Cie.)
Potential Gas Byproducts
- Carbon Dioxide (CO2)
- Sulfur Dioxide (SO2)
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