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Reactivity Documentation

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

mixed with

Nitrate and Nitrite Compounds, Inorganic

Summary

Details

Reactivity Predictions (for each pair of reactive groups)

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters mixed with
Nitrate and Nitrite Compounds, Inorganic

Hazard Predictions

Ethyl acetate reacts vigorously with oxidizers (Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 1570.), and esters have an undefined incompatibility with nitrates (Lewis 1547).

In general, nitrate and nitrite salts with redox active cations are more reactive with organic materials and reducing agents at ambient conditions. Redox active cations are transition metals and the metals in group 3a, 4a, and 5a of the periodic table and also include the ammonium cation NH4+. In general, nitrate and nitrite salts with non-redox active cations (also called spectator cations) are less reactive at ambient conditions. These include the alkali metals and alkaline earth salts. Caution should be used before proceeding. Further research of comparable examples in the literature or very small scale, carefully controlled experiments may be needed to fully assess compatibility.