Reactivity Documentation
Metals, Elemental and Powder, Active |
| mixed with |
Epoxides |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Polymerization hazard: Polymerization reaction may become intense and may cause pressurization
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Aldehydes
Details
Metals, Elemental and Powder, Active
is a reactive group.
Epoxides
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Metals, Elemental and Powder, Active
mixed with
Epoxides
Epoxides
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Polymerization hazard: Polymerization reaction may become intense and may cause pressurization
- Toxic: Reaction products may be toxic
Zinc or aluminum can initiate the exothermic polymerization of 1-chloro-2,3-epoxypropane (M. Sittig, 1981, Handbook of Toxic and Hazardous 365betÓéÀÖ, Park Ridge (NJ), Noyes Data Corp., 2nd ed., pp. 23).
Iron catalyzes isomerization of ethylene oxide to acetaldehyde, which is toxic and water-soluble (Denver, J.P., K.F. George, W.C. Hoffman, and H. Soo. 2001. Ethylene oxide. Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. (Online)).
Potential Gas Byproducts
- Aldehydes
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