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Hazard Predictions

• Generates heat: Exothermic reaction at ambient temperatures (releases heat)

Most combinations of alkali metals and less reactive metals only react at high temperatures or under special conditions (e.g. dissolving metal reduction in liquid ammonia), or form alloys. However, some exceptions were found:

Alkali metals react vigorously with tellurium (Hoffmann, J. E., King, M. G., Carapella, S. C., Oldfield, J. E. and Putnam, R. D. 2011. Tellurium and Tellurium Compounds. Kirk-Othmer Encyclopedia of Chemical Technology. 1-30. (Online)).

Lithium reacts violently with vanadium (Baroch, E. F. and Updated by Staff 2006. Vanadium and Vanadium Alloys. Kirk-Othmer Encyclopedia of Chemical Technology. (Online)).

Lithium and sodium react with arsenic at high temperatures to form metal arsenides (Pascal. P. 1963. Nouveau Trait茅 de Chimie Min茅rale. Vol. 2, Part 1, p. 116, 809. Masson et Cie.).

Alkali metals form alloys with mercury, bismuth, and thallium (Pascal. P. 1963. Nouveau Trait茅 de Chimie Min茅rale. Vol. 2, Part 1, p. 38. Masson et Cie.; DeVito, S. C. and Brooks, W. E. 2005. Mercury. Kirk-Othmer Encyclopedia of Chemical Technology. (Online); Breunig, H. J. 2002. Bismuth Compounds. Kirk-Othmer Encyclopedia of Chemical Technology. (Online); Micke, H. and Wolf, H. U. 2000. Thallium and Thallium Compounds. Ullmann's Encyclopedia of Industrial Chemistry).

Potassium forms an alloy with tungsten (Lassner, E., Schubert, W.-D., L眉deritz, E. and Wolf, H. U. 2000. Tungsten, Tungsten Alloys, and Tungsten Compounds. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).

Sodium and lithium form alloys with lead (Carr, D. S. 2000. Lead Compounds. Ullmann's Encyclopedia of Industrial Chemistry. (Online); King, M., Ramachandran, V., Prengaman, R. D., DeVito, S. C., Breen, J. and Updated by Staff 2005. Lead and Lead Alloys. Kirk-Othmer Encyclopedia of Chemical Technology. (Online)).