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Reactivity Documentation

Peroxides, Organic

mixed with

Aldehydes

Summary

Details

Peroxides, Organic is a reactive group.
Aldehydes is a reactive group.

Reactivity Predictions (for each pair of reactive groups)

Aldehydes mixed with
Peroxides, Organic

Hazard Predictions

Reactions of organic peroxides and aldehydes form explosive peroxy compounds (Sanchez, J., T.N. Meyers. 2000. Peroxides and Peroxide Compounds, Organic Peroxides. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons. (Online)).

Formaldehyde and peroxyformic acid react violently (D'Ans, J. et al. 1915. Berichte. 48:1136.).

The reaction of aldehydes and oxidizing acids may produce carboxylic acids which may decarboxylate, particularly for monoalkyl- or dialkylacetoacetic acids (Morrison, R. 1973. Organic Chemistry. Allyn and Bacon, Inc., Boston, pp. 630).

Strong oxidizing agents may decarboxylate aldehydes, releasing CO2 gas (Predicted).

Potential Gas Byproducts