Reactivity Documentation

Epoxides

mixed with

Nitrides, Phosphides, Carbides, and Silicides

Summary

Generates heat: Exothermic reaction at ambient temperatures (releases heat)
Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Polymerization hazard: Polymerization reaction may become intense and may cause pressurization

Details

Epoxides is a reactive group.

Nitrides, Phosphides, Carbides, and Silicides is a reactive group.

Reactivity Predictions (for each pair of reactive groups)

Epoxides mixed with
Nitrides, Phosphides, Carbides, and Silicides

Hazard Predictions

Generates heat: Exothermic reaction at ambient temperatures (releases heat)
Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Polymerization hazard: Polymerization reaction may become intense and may cause pressurization

The combination of epoxides and nitrides can lead to exothermic base-catalyzed ring-opening reactions, which can result in epoxide polymerization (Rich, Gerald A. Dangerous Chemical Reactions, Gulf Publishing Company: Houston, TX, 1993, p. 289).

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