Reactivity Documentation
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
mixed with |
Carbamates |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
-
May produce the following gases:
- Alcohols
- Aldehydes
- Ammonia
Details
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
is a reactive group.
Carbamates
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Carbamates
mixed with
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Carbamates are related to amides and esters, classes of compounds which can both be reduced by metal hydrides and metal alkyls to form a variety of products, depending on the reducing agent used. Possible products include aldehydes, alcohols, and amines. These reactions are highly exothermic at room temperature and can even occur at temperatures as low as -60 C (Kammermeier, B. 2012. Reduction. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).
Potential Gas Byproducts
- Alcohols
- Aldehydes
- Ammonia (NH3)