Reactivity Documentation
Acyl Halides, Sulfonyl Halides, and Chloroformates |
| mixed with |
Sulfonates, Phosphonates, and Thiophosphonates, Organic |
Summary
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Details
Acyl Halides, Sulfonyl Halides, and Chloroformates
is a reactive group.
Sulfonates, Phosphonates, and Thiophosphonates, Organic
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Sulfonates, Phosphonates, and Thiophosphonates, Organic
mixed with
Acyl Halides, Sulfonyl Halides, and Chloroformates
Acyl Halides, Sulfonyl Halides, and Chloroformates
Hazard Predictions
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Dimethyl sulfoxide reacts explosively with acetyl chloride or benzoyl chloride (Buckley, A. 1965. Journal of Chemical Education 42:674).
Dimethyl sulfoxide decomposes violently in contact with a wide range of acyl halides and related compounds, including cyanuric chloride, acetyl chloride, benzoyl chloride, benzenesulfonyl chloride, thionyl chloride, phosphoryl chloride, and phosphorus trichloride (Chem. Eng. News 35(9):87 (1957)).
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