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Reactivity Documentation

Organometallics

mixed with

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

Summary

Details

Organometallics is a reactive group.

Reactivity Predictions (for each pair of reactive groups)

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters mixed with
Organometallics

Hazard Predictions

When triiron dodecacarbonyl and ethyl 2,4-hexadienoate were combined, the product consisted of iron tricarbonyl coordinated to the double bonds, and the ester functionality remained unchanged (King, R.B., Manuel, T. A., Stone, F. G. A., J. lnorg. Nucl. Chem., 1961, Vol. 16, pp. 233 to 239).

Fe(CO)5 can deoxygenate sulfoxides to sulfides at 130 C, with release of CO2 gas (H. Alper, E. C. H. Keung, Tetrahedron Lett. 1970, 53).