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Hazard Predictions

• Flammable: Reaction products may be flammable
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Toxic: Reaction products may be toxic

Phenol reacts with bromine in aqueous solutions at ambient temperatures, producing toxic HCl as a byproduct (Solomons, T.W.G. 1984. Organic Chemistry, 3rd Edition. New York: John Wiley & Sons, Inc. pp. 685.).

Phenol reacts exothermically with Ca(OCl)2, producing toxic and flammable fumes, which can be ignited by reaction heat (Fawcett, H. 1959. Industrial and Engineering Chemistry Research 51:89A-90A.).

Phenol may explode violently if heated with NaNO2 (Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Oxford: Butterworth-Heinemann. pp. 1672.).

Phenols may liberate toxic and flammable aldehyde, ClO2, and Cl2, toxic halocarbon, flammable H2, and inert CO2 gases upon exposure to inorganic oxidizers (Predicted).

Potential Gas Byproducts

• Aldehydes
• Chlorine Dioxide (ClO2)
• Carbon Dioxide (CO2)
• Hydrogen (H2)
• Halogenated Organics
• Hydrogen Chloride (HCl)
• Acid Fumes