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Hazard Predictions

• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
• Toxic: Reaction products may be toxic

Phenol reacts exothermically with Ca(OCl)2, producing toxic and flammable fumes, which can be ignited by reaction heat (Fawcett, H. 1959. Industrial and Engineering Chemistry Research 51:89A-90A).

Phenol reacts with bromine in aqueous solution at ambient temperatures, producing toxic HBr as a byproduct (Solomons, T.W.G. 1984. Organic Chemistry, 3rd Edition. New York: John Wiley & Sons, Inc. pp. 685).

BrF3 ignites or explodes on contact with most organic compounds (Mellor, J.W. 1941. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Vol. 2, pp. 113; 1956. Volume 2, Supplemental 1. pp. 164-167).

Potential Gas Byproducts

• Hydrogen Chloride (HCl)
• Hydrogen Halide (HX)
• Acid Fumes