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Hazard Predictions

• Corrosive: Reaction products may be corrosive
• Explosive: Reaction products may be explosive or sensitive to shock or friction
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)

Ethyl and methyl carbamates form the potentially explosive N-carbomethoxyiminophosphoryl chloride with PCl5; the compound is stabilized by halogenated solvents (Mellor, J.W. 1971. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Vol. 8, Supp. 3, p. 589).

Carbamates may react with halogens to liberate toxic HX gases (Smith, P. A. S., Open-Chain Nitrogen Compounds, Vol. I. New York: W. A. Benjamin, Inc., 1965, pp. 201).

Potential Gas Byproducts

• Hydrogen Halide (HX)
• Acid Fumes