Reactivity Documentation
Oximes |
| mixed with |
Peroxides, Organic |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Aldehydes
- Nitrogen Oxides
Details
Oximes
is a reactive group.
Peroxides, Organic
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Peroxides, Organic
mixed with
Oximes
Oximes
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
Reactions of oximes with peroxides can produce ketones, aldehydes, and carboxylic acids, as well as gaseous nitrogen oxides. In some cases, the reaction proceeds under mild conditions (Cosaro, A.; Chiacchio, U.; Pistara, V. Regeneration of Carbonyl Compounds from the Corresponding Oximes. Synthesis. 2001, Vol. 13, p. 1903-1931). Oximes may oxidize to nitro compounds in the presence of certain peroxides.
Potential Gas Byproducts
- Nitrogen Oxides (NOx)
- Aldehydes
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