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Hazard Predictions

• Explosive: Reaction products may be explosive or sensitive to shock or friction
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Toxic: Reaction products may be toxic

NaN3 forms explosive solid BrN3 with bromine vapor (Mellor, J.W. 1940. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Vol. 8, pp. 336.).

Chlorine and hydrazine derivatives react to form nitrous acid chlorides and HCl (Franklin, E. C. The Nitrogen System of Compounds. New York: Reinhold Publishing Corporation. 1935. pp. 294). And by extension, the formation of other acidic gases is likely in the presence of their respective halogens (Predicted).

Potential Gas Byproducts

• Halogenated Amines
• Hydrogen Halide (HX)
• Acid Fumes