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Hazard Predictions

• Flammable: Reaction products may be flammable
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)

Carbamates liberate flammable H2 gas upon exposure to sodium metal (Smith, P. A. S., Open-Chain Nitrogen Compounds, Vol. I. New York: W. A. Benjamin, Inc., 1965, pp. 261).

Carbamate esters can be reduced by alkali metals to carbamate anions or to amines and alcohols (A. G. M. Barrett, P. Prokopiou, D. Barton, R. B. Boar, J. F. McGhie, Chem. Comm., 1979, p. 1173).

Potential Gas Byproducts

• Alcohols
• Hydrogen (H2)
• Ammonia (NH3)