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Diamond	Hazard	Value	Description
4 4 1	Health	4	Can be lethal.
	Flammability	4	Burns readily. Rapidly or completely vaporizes at atmospheric pressure and normal ambient temperature.
	Instability	1	Normally stable but can become unstable at elevated temperatures and pressures.
	Special

A clear colorless liquid with a faint odor of bitter almonds. Less dense than water. Vapors are slightly lighter than air. Vapors are very toxic by inhalation or skin contact. Prolonged exposure to heat can cause a closed container to rupture violently and rocket.

• Highly Flammable
• Polymerizable

Highly flammable. Reacts with water to release gaseous hydrogen cyanide (very poisonous).

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. CAUTION: Methanol (UN1230) will burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.) Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.). Vapor explosion and poison hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids will float on water. (ERG, 2024)

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears). Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or asphyxiation, especially when in closed or confined areas. Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2024)

HYDROGEN CYANIDE, SOLUTION IN ALCOHOL, WITH NOT MORE THAN 45% HYDROGEN CYANIDE reacts with acid to evolve hydrogen cyanide, a very poisonous colorless gas smelling of bitter almonds. The solution also evolves gaseous hydrogen cyanide when heated. Inhalation of the gas is quickly fatal by respiratory arrest. The gas forms flammable or explosive mixtures with air (may be difficult to ignite at lower concentrations), presents an explosion hazard when heated with or exposed to other oxidizing agents, and may polymerize explosively at elevated temperature (50-60掳C) or in the presence of traces of alkali [Wohler, L. et al., Chem. Ztg., 1926, 50, p. 761, 781]. Solution may react violently with acetaldehyde. Is incompatible with isocyanates, nitrides, peroxides, and epoxides. May react exothermically with metal salts. May generate flammable and/or toxic gases with alkali metals, nitrides, and strong reducing agents. During the preparation of imidoester hydrochlorides, hydrogen chloride was rapidly passed over an alcoholic solution of hydrogen cyanide. An explosion ensued, despite cooling of the process [J. Org. Chem., 1955, 20, 1573].

• Alcohols and Polyols
• Cyanides, Inorganic
• Acids, Weak
• Polymerizable Compounds

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

• Cellulose-Based Absorbents
• Mineral-Based & Clay-Based Absorbents
• Dirt/Earth

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.

SPILL: See ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 3294 datasheet.

FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

CAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient. CAUTION: Methanol (UN1230) will burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.).

SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam.

LARGE FIRE: Water spray, fog or alcohol-resistant foam. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal. Avoid aiming straight or solid streams directly onto the product.

FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2024)

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors.

SMALL SPILL: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Use clean, non-sparking tools to collect absorbed material.

LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2024)

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)

Normalized Breakthrough Times (in Minutes)

Chemical	CAS Number	State	QS	QC	SL	C3	TF	TP	RC	TK	RF
Hydrogen cyanide (21掳C, liquid)	74-90-8	Liquid							135	>480	135
Hydrogen cyanide (27掳C, gaseous)	74-90-8	Vapor				30			>480	>480	>480
Ethanol	64-17-5	Liquid			>480	>480	>480	>480	>480
Ethyl alcohol	64-17-5	Liquid			>480	>480	>480	>480	>480
Spiritus	64-17-5	Liquid			>480	>480	>480	>480	>480

Special Warning from DuPont: Tychem庐 and Tyvek庐 fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...

(DuPont, 2024)

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

Refer to the "General First Aid" section. Specific First Aid: Wash skin with soap and water. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. (ERG, 2024)

• HYDROGEN CYANIDE, SOLUTION IN ALCOHOL, WITH NOT MORE THAN 45% HYDROGEN CYANIDE