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Potassium chromate is a yellow crystalline solid. It is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is used in chemical analysis, in making pigments for paints and inks, as a fungicide, and to make other chromium compounds.

• Strong Oxidizing Agent

Soluble in water.

Behavior in Fire: May increase intensity of fire if in contact with combustible materials. Cool containers and spilled material with plenty of water. (USCG, 1999)

Inhalation causes local irritation of mucous membranes; continuing nose irritation can result in perforation of nasal septum. Ingestion may cause violent gastroenteritis, circulatory collapse, vertigo, coma, and toxic nephritis; ingestion of excessive quantities can be fatal. Contact with eyes causes severe irritation and conjunctivitis. Repeated or prolonged exposure to dust, mist, or solutions may cause dermatitis; contact with breaks in the skin may cause "chrome sores" appearing as slow-healing, hard-rimmed ulcers which leave the area vulnerable to infection. (USCG, 1999)

Oxidizing agents, such as POTASSIUM CHROMATE, can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air). The chemical reduction of materials in this group can be rapid or even explosive, but often requires initiation (heat, spark, catalyst, addition of a solvent). Explosive mixtures of inorganic oxidizing agents with reducing agents often persist unchanged for long periods if initiation is prevented. Such systems are typically mixtures of solids, but may involve any combination of physical states. Some inorganic oxidizing agents are salts of metals that are soluble in water; dissolution dilutes but does not nullify the oxidizing power of such materials. Organic compounds, in general, have some reducing power and can in principle react with compounds in this class. Actual reactivity varies greatly with the identity of the organic compound. Inorganic oxidizing agents can react violently with active metals, cyanides, esters, and thiocyanates.

• Salts, Basic
• Oxidizing Agents, Strong

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

• Cellulose-Based Absorbents
• Expanded Polymeric Absorbents

Excerpt from ERG Guide 140 [Oxidizers]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).

FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. If ammonium nitrate products are in a tank, rail car or truck and involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions. (ERG, 2024)

Excerpt from ERG Guide 140 [Oxidizers]:

SMALL FIRE: Use water. Do not use dry chemicals or foams. CO2 or Halon庐 may provide limited control.

LARGE FIRE: Flood fire area with water from a distance. Do not move cargo or vehicle if cargo has been exposed to heat. If it can be done safely, move undamaged containers away from the area around the fire.

FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: For ammonium nitrate products: Do not fight cargo fire. Withdraw, evacuate and isolate area for at least 1600 meters (1 mile). Treat as an explosive (ERG Guide 112). Do not enter area for 24 hours or until expert advice has been provided. Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ALWAYS stay away from tanks in direct contact with flames. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2024)

Excerpt from ERG Guide 140 [Oxidizers]:

Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Do not get water inside containers.

SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.

SMALL LIQUID SPILL: Use a non-combustible material like vermiculite or sand to soak up the product and place into a container for later disposal.

LARGE SPILL: Dike far ahead of liquid spill for later disposal. (ERG, 2024)

Bu. of Mines approved filter-type respirator; close-fitting safety goggles; rubber boots and apron; safety hat; face shield (USCG, 1999)

Normalized Breakthrough Times (in Minutes)

Chemical	CAS Number	State	QS	QC	SL	C3	TF	TP	RC	TK	RF
Potassium chromate (sat)	7789-00-6	Liquid			>480		>480	>480	&驳迟;480鈦�	&驳迟;480鈦�	&驳迟;480鈦�

Special Warning from DuPont: Tychem庐 and Tyvek庐 fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...

(DuPont, 2024)

INHALATION: move to fresh air.

INGESTION: give large amount of water; induce vomiting; treat peripheral vascular shock vigorously; get medical attention.

EYES: flush with water for at least 15 min.; get medical attention.

SKIN: flush with water; if irritation persists, get medical attention. (USCG, 1999)

• BIPOTASSIUM CHROMATE
• DIPOTASSIUM CHROMATE
• DIPOTASSIUM CHROMATE (K2CRO4)
• DIPOTASSIUM CHROMATE(2-)
• DIPOTASSIUM MONOCHROMATE
• NEUTRAL POTASSIUM CHROMATE
• POTASSIUM CHROMATE
• POTASSIUM CHROMATE (K2(CRO4))
• POTASSIUM CHROMATE (VI)
• POTASSIUM CHROMATE(VI)