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Cyclotrimethylene trinitramine is an explosive. The explosion can be initiated by a sudden shock, high temperature or a combination of the two. The primary hazard is from blast effect and not from flying projectiles and fragments. Under prolonged exposure to heat or fire they can explode.

• Explosive

Insoluble in water.

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

MAY EXPLODE AND THROW FRAGMENTS 1600 METERS (1 MILE) OR MORE IF FIRE REACHES CARGO. (ERG, 2024)

Excerpt from NIOSH Pocket Guide for Cyclonite:

Exposure Routes: Inhalation, skin absorption, ingestion, skin and/or eye contact

Symptoms: Irritation eyes, skin; headache, irritability, lassitude (weakness, exhaustion), tremor, nausea, dizziness, vomiting, insomnia, convulsions

Target Organs: Eyes, skin, central nervous system (NIOSH, 2024)

CYCLOTRIMETHYLENE TRINITRAMINE is incompatible with strong oxidizing agents, combustible materials and heat. Detonates on contact with mercury fulminate (NIOSH, 2024). Danger of explosion when dry. The self heating and explosive decomposition of the explosive and aqueous alkali (calcium hydroxide) has been studied, [Chem Abs., 1988, 109, 112968].

• Azo, Diazo, Azido, Hydrazine, and Azide Compounds
• Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

• Cellulose-Based Absorbents
• Expanded Polymeric Absorbents

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in all directions.

LARGE SPILL: Consider initial evacuation for 800 meters (1/2 mile) in all directions.

FIRE: If rail car or trailer is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions. (ERG, 2024)

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

CARGO FIRE: DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let burn. Do not move cargo or vehicle if cargo has been exposed to heat.

TIRE OR VEHICLE FIRE: Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt. If possible, and WITHOUT RISK, use unmanned master stream devices or monitor nozzles from maximum distance to prevent fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by, at a safe distance, with extinguisher ready for possible re-ignition. (ERG, 2024)

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 METERS (330 FEET) OF ELECTRIC DETONATORS. DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (ERG, 2024)

Excerpt from NIOSH Pocket Guide for Cyclonite:

Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.

Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.

Wash skin:
鈥� WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.
鈥� DAILY - The worker should wash daily at the end of each work shift, and prior to eating, drinking, smoking, etc.

Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.

Change: DAILY - Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises.

Provide:
鈥� EYEWASH - Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances; this is irrespective of the recommendation involving the wearing of eye protection.
鈥� QUICK DRENCH - Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2024)

No information available.

Excerpt from NIOSH Pocket Guide for Cyclonite:

Eye: IRRIGATE IMMEDIATELY - If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

Skin: SOAP FLUSH IMMEDIATELY - If this chemical contacts the skin, immediately flush the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. If irritation persists after washing, get medical attention.

Breathing: RESPIRATORY SUPPORT - If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the affected person warm and at rest. Get medical attention as soon as possible.

Swallow: MEDICAL ATTENTION IMMEDIATELY - If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2024)

• A 3
• A 3 (EXPLOSIVE)
• COMPOSITION A 3
• CPX 301
• CX 84A
• CYCLONITE
• CYCLOTRIMETHYLENE TRINITRAMINE, [DESENSITIZED]
• CYCLOTRIMETHYLENENITRAMINE
• CYCLOTRIMETHYLENETRINITRAMINE
• HEXAHYDRO-1,3,5-TRINITRO-1,3,5-S-TRIAZINE
• HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE
• HEXAHYDRO-1,3,5-TRINITRO-S-TRIAZINE
• HEXOGEN
• HEXOGEN (EXPLOSIVE)
• HEXOGEN 5W
• PBX 9407
• PBX(AF) 108
• PBX-B 2238
• PBX-C 117
• PBX-L 3
• PBX-L 5
• PBX-MC
• PBX-MVF
• PBX-W 108
• PBXN 107
• PBXN 107A
• PBXN 108
• PBXN 201
• PBXN 6
• PBXN(AF) 108
• PBXW 108(E)
• PE 4
• PE 4 (EXPLOSIVE)
• PHX 34
• RDX
• S-TRIAZINE, HEXAHYDRO-1,3,5-TRINITRO-
• T4
• 1,3,5-TRIAZA-1,3,5-TRINITROCYCLOHEXANE
• TRIMETHYLENETRINITRAMINE
• 1,3,5-TRINITRO-1,3,5-TRIAZACYCLOHEXANE
• 1,3,5-TRINITROHEXAHYDRO-1,3,5-TRIAZINE
• 1,3,5-TRINITROHEXAHYDRO-S-TRIAZINE
• 1,3,5-TRINITROPERHYDRO-1,3,5-TRIAZINE
• TS 1
• TS 1 (PROPELLANT)
• V 29
• V 29 (PROPELLANT)